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F Orbital Shape: Definitions, Orbital Chemistry, Atomic Orbitals, Examples, Shape, Characteristics, and Types

Nikita Parmar

Updated on 21st August, 2023 , 4 min read

F Orbital Shape Overview

The orbitals that may hold a total of 14 electrons in them are called F orbitals. The f orbital has a tetrahedral structure. Despite having a more complicated form than the other orbitals, the f orbital filling rule is the same as for the p and d orbitals. It was also discovered that the orientation of the electrons matches that of the other two orbitals. When fully filled, the F orbital resembles the D orbital. But when f orbitals are divided in half, eight lobes rather than the four observed in d orbitals are discovered

What is Orbital Chemistry?

There are four main types of orbitals, each having a unique form and designated by the letters s, p, d, and f. S and p orbitals are taken into consideration out of the four since they are more prevalent in chemical and biological chemistry. A p-orbital has a dumbbell form, a d-orbital has a spherical shape with the nucleus at its core, and four of the five d orbitals have a cloverleaf shape. The fifth d orbital has a doughnut-shaped center and is formed like an extended dumbbell. An atom's orbitals are arranged into several electron shells or layers.

F Orbital Shape

Read more about the Father of Chemistry and the Chemistry Periodic Table.

What are Atomic Orbitals?

Atomic orbitals are the regions of a 3-dimensional space surrounding an atom's nucleus where the likelihood of encountering an electron is greatest. There are several orbitals in an atom. Furthermore, there are different forms for these orbitals. A smaller orbital size increases the likelihood of detecting an electron close to the nucleus.

F Orbital Shape

What is F Orbital?

The f block has a special sequence. It introduces a 15-element block with lanthanum (Z = 57) as the first element. A tetrahedron's fifth level has 15 units. The f block has 15 elements (Z = 57 to 71), however, an odd number (14 / 2 = 7) impacts the number of orbitals. In order to make up for this, starting with the fifth d block, it turns a proton into a neutron.

F Orbital Shape

What is the F Orbital Shape?

Despite being more complicated, the f orbital adheres to the same guidelines for proton alignment as the p and d orbitals. When fully filled, it resembles the D orbital but is sliced in half (having eight lobes rather than four). It is based on the locations in the rotation of the nucleus where the gluons of protons with opposing spins align.

F Orbital Shape

Example of F Orbital Shape

The overall form of the f orbital is tetrahedral.

The Shape of F Orbital

The orbital's form is quite intricate. Despite the complexity of the form, the electron-filling rule does not change. The protons align according to the same rules as all other and d orbitals. The f orbital only mimics the form of the d orbital when it is fully filled. The f orbital, however, splits into 8 lobes as opposed to the anticipated 4 lobes when it is divided in half. The protons with opposing spins align on the sites of the nucleus rotation, which is the basis for the splitting of the lobes. The f orbital's shape is scattered. The fundamental quantum number n has a minimum value of 4, as l = 3 for the f orbital. 

The f orbital's corresponding ml values are (-3, -2, -1, 0, +1, +2, +3). 

Therefore, for l = 3, there are seven f orbitals.

Read more about the Electronic Configuration of the First 30 Elements, Formal Charge Formula, and Named Reactions.

Characteristics of F Orbital Shape

The f orbital shape has a tetrahedral structure. Despite having a more complicated form than the other orbitals, the f orbital shape-filling rule is the same as for the p and d orbitals. It was also discovered that the orientation of the electrons matches that of the other two orbitals.

Read more about the First 20 Elements in the Periodic Table, Types of Hybridization, and Orbital Velocity Formula.

Types of F Orbital Shape

Based on how they are positioned on the axis, the f orbitals shape are of three types  - 

  1. Two Lobes: Only sigma bonding occurs in two lobes types of f orbitals. It can help bind heads to heads along the z-axis because only sigma bonding is present. 
  2. Six Lobes: Either simply fi bonding, or pie and sigma bonding, are present in the six-lobe type of f orbitals. Along the y axes, XY planes, and z axes, the pi bond can create a bond. 
  3. Eight Lobes: Types of f orbitals with eight lobes can produce pi bonds or delta bonds. Any of the axes can be used to build the pie bond, or it can instead establish a delta bond with another f orbital to create a bimetallic complex.

Frequently Asked Questions

What form does the orbital have?

Ans. The overall form of the f orbital is tetrahedral.

How many different f orbital kinds are there?

Ans. There are three different kinds of orbitals.

In chemistry, how many orbitals are there?

Ans. In chemistry, there are four distinct sizes of orbitals (s, p, d, and f), and each orbital may hold up to two electrons. There are different sub-levels in the orbitals p, d, and f, so they can hold more electrons. According to its location on the periodic table, each electron in an element’s arrangement is distinct.

What orbitals possess the most energy?

Ans. The greatest energy and outermost orbital have the behavior of 4s.

What level does the f orbital belong to?

Ans. The f orbital is the fourth level of the atomic orbital.

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